Precision in Microscale Titration

High Precision Coulometric Titration of Uranium

An improved method for the coulometric assay of uranium and uranium oxide has been developed based on the electrogeneration of Tif II in H2SO,, using Fe(lI) as a catalyst. The endpoint is determined amperometrically. Hydrogen peroxide is used as the oxidant in the dissolution of the uranium to avoid interferences from nitrate. The precision of the method as indicated by the standard deviation o...

Titration Calorimetry Standards and the Precision of Isothermal Titration Calorimetry Data

Current Isothermal Titration Calorimetry (ITC) data in the literature have relatively high errors in the measured enthalpies of protein-ligand binding reactions. There is a need for universal validation standards for titration calorimeters. Several inorganic salt co-precipitation and buffer protonation reactions have been suggested as possible enthalpy standards. The performances of several com...

A compact automated titration system, applied to a high-precision determination of calcium in sea-water

Recent advances in microscale separation.

This review focuses on the recent advances on microscale separation technology, particularly on the new development on column and detection technologies in electrophoretic and chromatographic separation modes (i.e., CE, CEC, cLC, etc.). Representative examples illustrate also applications on the small molecules, peptides, proteins, polysaccharides, chiral and so on. 246 relevant articles are ci...

Coulometric Titration with Electrogenerated Tin(II). Titration of Platinum(IV)